• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to chemical methods for controlling undesirable vegetation. The invention makes it possible to increase the activity by 60-100% with respect to monocotyledon and dicotyledonous plants through the use of diazolinone derivatives of the formula N = C (2-COQR 3 -PHX) -NH-CR 1 R 2 -CO, where Q is oxygen , X - hydrogen, chlorine, nitro in position 3 or 6, methyl in position 4 or 5 R 1 - methyl, ethyl R 2 - ethyl, isopropyl, or R 1 and R 2 jointly pentamethylene or 1-methyl pentamethylene R 3 is hydrogen, sodium, methyl, ethyl, propyl, tert-butyl, 1,1-dimethylpropyl, n-hexyl, n-octyl, n-dodecyl, 2-propenyl, 1-methyl-2-propenyl, 1,1 -dimethyl-2-propenyl, 2-methyl-2-propenyl, 1,1-diethyl-2-propenyl, divinylmethyl, 1,1-diisopropyl-2-propenyl, 2-butenyl, 3-methyl-2-butenyl, 2 -ethoxyethyl, 3-phenyl-2-propenyl, 2-methoxyethyl, 1-cyclopropylethyl, benzyl, 3-cyclohexenylmethyl, 1-methyl-2-butenyl, 1-ethynylcyclohexyl, 2-isopropyl-5-methylcyclohexyl, furan-2-yl -methyl, 2-propynyl, 1,1-dimethyl-2-propynyl, 1-methyl-2-propinyl, 3-butynyl, 3-phenyl-2-propynyl, 1-methyl-2-propynyl, 3-butynyl, 3 -phenyl-2-pr opinyl, 1,1-isopropinyl-2-propynyl, 2-dekinyl, 2-butynyl-4-ol, 2,2,2-trichloroethyl, 2-chloro-2-propenyl, and, if X is different from hydrogen, then as mixtures of two isomers, different in the position of X in the benzene ring, if QR 3 is amino, methylamino, dimethylamino, propylamino, then X-hydrogen R 1 is methyl R 2 - isopropyl or R 1 and R 2 together pentamethylene, or their chlorides, in a dose of 0.07-11.2 kg / ha compared with 4-bromo-4- (2,4-dichlorobenzoyl) -1.3- dimethyl-2-pyrazolin-5-one.
    公开号:SU1480750A3
    申请号:SU2646369
    申请日:1978-08-08
    公开日:1989-05-15
    发明作者:Лос Маринус
    申请人:Американ Цианамид Компани (Фирма)；
    IPC主号:
    专利说明:

    I
    The invention relates to chemical methods of washing plants, specifically to a method of controlling weeds by treating plants or their bio-current with a derivative of diazolinone.
    The aim of the invention is to increase the efficiency of the method.
    Derivatives of diazolinone, which are used in this method, semi
    cm
    is prepared by reacting a compound of the formula
    N .0
    in which X, R and Eg have the indicated values, with the corresponding alkali metal alkoxy (when R e is not hydrogen, and O is oxygen), or hydrochloric acid (Q is oxygen, R 3 is hydrogen), or amine (QR3 - amino group).
    In this way, compounds of the indicated formula are obtained, presented in Tables 1 and 2.
    The high herbicidal activity of this method is shown below as compared to the known ones using 41-bromo-4- (2,4-dichlorbene oyl) -, 3-dime-i tyl-2-pyrazolin-5-one (compound A). Example 1. Monocotyledonous and dicotyledonous plants and sedge species are treated with the test compound dispersed in a water-acetone mixture. In these tests, the seedlings of the plants are grown in individual pots for approximately 2 weeks before they are treated with the appropriate compounds. Test compounds are dispersed in mixtures of acetone and water (50:50) containing 0.5% Tween 20 (polyoxyethylenorbitan monolaurate) in such an amount to provide 0.07–11.2 kg / ha of active compound. The plants are treated with a laboratory sprayer with a power belt by spraying through a nozzle operating at a pressure of 2.8 MPa for a predetermined time. After spraying, the plants are placed in a greenhouse. Two weeks after treatment, the sprouts, with the exception of oats, which are studied five weeks later, are examined and evaluated according to the scoring system below. The data are given in Table 3 (the herbicidal activity in the period after germination of the plants).
    scores
    % difference in growth from control (based on the visual determination of grass, size, power
    0 g 5
    0
    five
    0
    five
    50
    55
    chlorosis, growth deformations and the general external state of plants)
    0- no effect
    1- possible effect1-10
    2- weak effect11-25
    3- moderate effect26-40
    5 - pronounced lesion41-60
    6- herbicidal effect61-75
    7- good herbicidal egnfect76-90
    8- pai i complete suppression91-99
    complete suppression or destruction100
    4 - abnormal growth,
    those. pronounced physiological deformity, but with a general effect of less than 5 on the accepted scale.
    The following abbreviations are used in Table 3:
    PN - Cyperus rotundus L;
    SE - Sesbania exaltata;
    MU - Brassica kaber;
    PI - Amaranthus retroflexus;
    RW - Ambrosia artemisiifolia;
    MG - Ipomoea purpurea;
    BA - Echinochloa crusgalli;
    CR - Digitaria sanguinalis;
    FO - Setaria viridis;
    VO - Avena fatus;
    TW - Sida sponosa;
    VL - Abivtilon theophrasti;
    CN - Zea mays;
    CO - Gossynium hirsutum;
    SY - Glycine max;
    RI - Oryza sativa;
    SW - Triticum acstivum;
    SB - Hordcum vilgare.
    Example 2. Seeds of monocotyledonous, sedge, and dicotyledonous plants are separately mixed with soil to fill the pots and approximately 2.5 cm of soil is planted on top of the pots. After planting, the pots are sprayed with a selected water-acetone solution containing the test compound. Treated pots then
    placed on the shelves of the greenhouse, watered. 3-4 weeks after the treatment, the tests are stopped and each pot is examined and points are given in accordance with the evaluation system described in Example 1. The data are presented in Table 4 (the herbicidal activity during the period before the germination of the plants).
    Thus, the proposed method is highly effective with small doses.
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    A method of controlling weeds by treating plants or their biotope with diazolinone derivatives, characterized in that, in order to increase the efficiency of the method, a compound of the formula
    N where, if Q is oxygen, then
    X is hydrogen, chlorine, nitro group in position 3 or 6, methyl in position 4 or 5; R, is methyl, ethyl; RЈ - ethyl, isopropyl or R, and} .Ј jointly - pentamethylene or 1-methyl-pentamethylene,
    R5 is hydrogen, sodium, methyl, ethyl, propyl, tert-butyl, 1,1-dimethylprop5, n-hexyl, n-octyl,
    N. dodecyl, 2-propenpl, 1-methyl-2-propenyl, 1,1-dimethyl-2-propensh, 2-methyl-2-propenyl,
    01.1-diethyl-2-prog,
    divinyl-methyl, 1,1-di-isopropyl-2-propenyl, 2-butenyl, 3-methyl-2-butenyl, 2-ethoxyethyl, 5Z-phenyl-2-propenyl,
    2-methoxyethyl, 1-cyclopropylethyl, benzyl, 3-cyclohexenylmethyl, 1-methyl-2-butenyl, 1-0-ethylcyclohexide,
    2-isoprogyl-5-methyl-cyclohexyl, furan-2-yl-methyl, 2-propinyl, 1 -1-dimethyl-2-propinyl,
    5-methyl-2-propinyl, 3-
    butynyl, 3-phenyl-2-propynyl, 1,1-isopropyl-2-propynyl, 2-decinyl, 2-butynyl-4-ol, 2,2,2-0-trichloroethyl, 2-chloro-2propenyl;
    moreover, if X is different from hydrogen, then in the form of mixtures of two isomers, which differ in the position of X in the benzene ring; if QR is amino, methylamino, dimethylamino, propyl mino, then X is bovine, R (is methyl, R2 is isopropyl or K and K2 together is pentamethylene, or their chlorides, in an amount of 0.07-0.2 / kg / ha
    Table 1
    , COOR3
    Continuation of table
    eleven
    U80750
    1 2 Continued tab.
    A mixture of two isomers (position X in the benzene ring is indicated).
    Table 2
    Continued tabl,
    Continuation of table 3
    Continuation of table 3
    Table
    类似技术:
    公开号 | 公开日 | 专利标题
    RU2002419C1|1993-11-15|Method of selective inhibition of undesirable flora
    JPH07112981A|1995-05-02|Triazine derivative and herbicide containing the same as active ingredient
    US3175897A|1965-03-30|Asymmetric thiolcarbamates as herbicides
    US2923634A|1960-02-02|Method of controlling undesirable plant growth
    SU1480750A3|1989-05-15|Method of weed control
    US4032657A|1977-06-28|Haloacetanilides as microbicidal active substances
    SU728687A3|1980-04-15|Weeds fighting method
    SU1169516A3|1985-07-23|Method of fighting undesirable plants
    SU493056A3|1975-11-25|Herbicidal composition
    SU1553006A3|1990-03-23|Method of controlling unwanted vegetation
    SU629851A3|1978-10-25|Method of fighting unwanted plant growth
    SU440815A1|1974-08-25|HERBICIDE STRUCTURE
    US3046104A|1962-07-24|Method for the control of weeds
    SU965338A3|1982-10-07|Herbicidal composition
    US4208203A|1980-06-17|Method of protecting corn from herbicides
    SU784770A3|1980-11-30|Method of preparing cyclopropane carboxylic acid anilidies
    US3246976A|1966-04-19|Method for controlling crab grass and water grass
    SU725541A1|1980-03-30|Herbicidic agent
    SU1111673A3|1984-08-30|Method for controlling wild plants
    SU465766A3|1975-03-30|Herbicide
    SU1482508A3|1989-05-23|Method of fighting unwanted vegetation
    RU1814518C|1993-05-07|Herbicidal composition and method for controlling weeds
    US3493360A|1970-02-03|Herbicides
    SU542445A3|1977-01-05|The way to combat unwanted vegetation
    SU607527A3|1978-05-15|Herbicide
    同族专利:
    公开号 | 公开日
    US4122275A|1978-10-24|
    ZA783834B|1979-07-25|
    PH14271A|1981-04-29|
    RO75257A|1980-11-30|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE1176660B|1963-07-05|1964-08-27|Beiersdorf & Co A G P|Process for the preparation of triaryl-substituted imidazolinones-4 |
    US3645965A|1967-10-23|1972-02-29|Sankyo Co|Stabilization of synthetic polymers with imidazolidine compounds|
    US3687971A|1970-06-22|1972-08-29|Merck & Co Inc|4--salicylic acid derivatives|US4297128A|1978-06-09|1981-10-27|American Cyanamid Co.|Use of imidazolinyl benzoates as herbicidal agents|
    US4297126A|1978-01-09|1981-10-27|American Cyanamid Co.|Imidazolinyl benzamides as plant growth regulants|
    US4170462A|1978-01-23|1979-10-09|American Cyanamid Company|Method for controlling the relative stem growth of plants|
    US4221586A|1979-01-30|1980-09-09|American Cyanamid Company|Imidazolinyl benzamides as herbicidal agents|
    DE3340594A1|1983-11-10|1985-05-23|Hoechst Ag, 6230 Frankfurt|2-ARYL-SUBSTITUTED IMIDAZOLINONES, METHOD FOR THEIR PRODUCTION AND THEIR USE IN PLANT PROTECTION|
    US4726835A|1985-12-02|1988-02-23|Idemitsu Kosan Company Limited|Herbicidal and plant growth regulating imidazoline derivatives|
    EP1066262A4|1998-03-25|2004-09-01|Squibb Bristol Myers Co|Imidazolone anorectic agents: i. acyclic derivatives|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US05/822,459|US4122275A|1977-08-08|1977-08-08|Imidazolinyl benzamides as herbicidal agents|
    [返回顶部]